Preparation and Solid-State Characterization of 1,2,3,5-Diselenadiazolyl [Hcn2se2]

by Cordes, A. W.; Glarum, S. H.; Haddon, R. C.; Hallford, R.; Hicks, R. G.; Kennepohl, D. K.; Oakley, R. T.; Palstra, T. T. M.; Scott, S. R.

The reaction of N,N,N'-tris(trimethylsilyl)formamidine with SeCl2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN2Se2].; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.

Journal
Journal of the Chemical Society-Chemical Communications
Issue
17
Year
1992
Start Page
1265-1266
URL
https://dx.doi.org/10.1039/c39920001265
ISBN/ISSN
0022-4936
DOI
10.1039/c39920001265