The Reaction of Cpru(pph3)2+ with Trimethylenesulfide - Synthesis and Molecular and Crystal-Structure of [Cpru(pph3)2(sc3h6)]cf3so3

by Park, Haengsoon; Draganjac, Mark; Scott, Syrona Renae Horton; Cordes, A. Wallace; Eggleton, Gordon

The isolation and characterization of the trimethylenesulfide-coordinated complex, [CpRu(PPh3)2(SC3H6)]CF3SO3, is reported. The structure of [CpRu(PPh3)2(SC3H6)]CF3SO3 was determined by X-ray diffraction techniques: monoclinic space group I2/a, a = 23.864(10), b = 14.233(3), c = 24.385(7) angstrom, beta = 97.10(3)degrees, Z = 8, R = 0.046, R(w) = 0.065. The Ru is attached to two triphenylphosphine ligands, a cyclopentadienyl and the trimethylenesulfide. The Ru-S distance is 2.3459(20) angstrom.

Journal
Inorganica Chimica Acta
Volume
221
Issue
1-2
Year
1994
Start Page
157
ISBN/ISSN
1873-3255; 0020-1693
DOI
10.1016/0020-1693(94)03952-6