Crystal and Molecular-Structure of [Cpru(pph3)2(t-C4h9sh)]bf4

by Minick, David; Draganjac, Mark; Crump, J. W.; Cordes, A. Wallace

The structure of the [CpRu(PPh3)2(t-C4H9SH)]BF4 complex was determined by X-ray diffraction techniques: monoclinic space group P2(1)/c, a = 14.662(9), b = 18.515(7), c = 15.368(6)angstrom, beta = 101.88(5)-degrees, V = 4082(6)angstrom3, Z = 4, R = 0.049, R(w) = 0.057. The Ru is attached to two tfiphenylphosphine ligands, a cyclopentadienyl and the t-butylmercaptan. The Ru-S distance is 2.396(2)angstrom and the S-H distance is 1.289(2)angstrom.

Journal
Journal of Crystallographic and Spectroscopic Research
Volume
23
Issue
8
Year
1993
Start Page
629
ISBN/ISSN
1572-8854; 0277-8068
DOI
10.1007/BF01325185