A pi-stacked 1,2,3-dithiazolyl radical. Preparation and solid state characterization of (Cl2C3NS)( ClC2NS2)

by Beer, Leanne; Cordes, A. Wallace; Haddon, Robert C.; Itkis, Mikhail E.; Oakley, Richard T.; Reed, Robert W.; Robertson, Craig M.

Crystals of (Cl2C3NS)(ClC2NS2), an isothiazolyl-substituted 1,2,3-dithiazolyl radical, consist of evenly spaced, slipped pi-stacks; magnetic and conductivity measurements indicate the material is a Mott insulator with sigma(RT) = 2 x 10(-7) S cm(-1).