The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDA. [Erratum to document cited in CA151:425101]
by Coldham, Iain; Leonori, Daniele; Beng, Timothy Kum; Gawley, Robert E.
In the original manuscript and supplementary information, the kinetics equations erroneously included a factor of 0.5, which affected the subsequent calculations of rate constants. A nonlinear fit to zero order plots has been used to calculate all the rate constants, affording the revised inversion parameters given herein. The supplementary information has been corrected, and revisions to Table 1, Figure 1, Figure 2 and Figure 2 supporting text are provided.