Copper(ii) and Cobalt(ii) Complexes of 2,2-Diphenyl-4,4,6,6-Tetrakis(1-Pyrazolyl)cyclotriphosphazene, N(3)p(3)ph(2)pz(4) - X-Ray Crystal-Structure of N(3)p(3)ph(2)pz(4)center-Dot-Cocl2-Center-Dot-0.5ch(2)cl(2)

by Thomas, K. R. Justin; Chandrasekhar, Vadapalli; Scott, Syrona Renae Horton; Cordes, A. Wallace

Synthesis and characterization of isotypical compounds N(3)P(3)Ph(2)Pz(4) . MX(2) (M = Cu, X = Cl or Br; M = Co, X = Cl) are reported. The X-ray crystal structure of N(3)P(3)Ph(2)Pz(4) . CoCl2 . 0.5CH(2)Cl(2) is described. The structure is a distorted trigonal bipyramid in which the cobalt atom is coordinated by a ligand molecule through the two nongeminal pyrazolyl pyridinic nitrogens at the equatorial sites and a cyclophosphazene ring nitrogen at the axial position. The remaining axial and equatorial positions are occupied by the two chlorine atoms.

Journal
Polyhedron
Volume
14
Issue
12
Year
1995
Start Page
1607
ISBN/ISSN
1873-3719; 0277-5387
DOI
10.1016/0277-5387(94)00434-G