A bis(1,2,3-dithiazole) charge transfer salt with 2: 1 stoichiometry; inhibition of association and generation of slipped π-stacks

by Barclay, Tosha Madeva; Cordes, A. Wallace; Mingie, James R.; Oakley, Richard T.; Preuss, Kathryn E.

The 1st example of a charged transfer salt of a benzo-bridged bis(1,2,3-dithiazole) with 2:1 stoichiometry is reported; the steric bulk of the chlorines at the 3,6-positions of the benzene ring induces slipped π-stacks of dimer radical cations. Crystallog. data are given for dichlorobenzo[1,2-d:4,5-d']bis[1,2,3]dithiazolediium tetrachlorogallate.

Journal
CrystEngComm
Year
2000
Start Page
Article No. 15
ISBN/ISSN
1466-8033
DOI
10.1039/B004239K