CHBC Faculty Publications

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Author: Gawley, Robert E.

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TitlePublication NamePub. TypeYear
Toward the reproducibility of CuIPhEt hydrosilylationsAbstracts of Papers, 249th ACS National Meeting and Exposition, Denver, CO, United States, March 22-26, 2015Abstract2015
Improved synthesis and expanded application of CuIPhEt, a C2-symmetric N-heterocyclic carbenoidAbstracts of Papers, 246th ACS National Meeting and Exposition, Indianapolis, IN, United States, September 8-12, 2013Abstract2013
Double-Asymmetric Hydrogenation Strategy for the Reduction of 1,1-Diaryl Olefins Applied to an Improved Synthesis of CuIPhEt, a C-2-Symmetric N-Heterocyclic CarbenoidJournal of Organic ChemistryJournal Article2013
Catalytic Dynamic Resolution Applied to the Synthesis of 2,6-Disubstituted Piperidines: Preparation of (+)-Lupetidine and (-)-EpidihydropinidineHeterocyclesJournal Article2012
Dynamics of Catalytic Resolution of 2-Lithio-N-Boc-piperidine by Ligand ExchangeJournal of the American Chemical SocietyJournal Article2012
Synthetic Applications and Inversion Dynamics of Configurationally Stable 2-Lithio-2-arylpyrrolidines and -piperidinesJournal of the American Chemical SocietyJournal Article2012
Introduction, General Principles, and Glossary of Stereochemical TermsPrinciples of Asymmetric SynthesisBook, Section2012
Practical Aspects of Asymmetric SynthesisPrinciples of Asymmetric SynthesisBook, Section2012
Enolate, Azaenolate, and Organolithium AlkylationsPrinciples of Asymmetric SynthesisBook, Section2012
1,2- and 1,4-Additions to C=X BondsPrinciples of Asymmetric SynthesisBook, Section2012
Aldol and Michael Additions of Allyls, Enolates, and Enolate EquivalentsPrinciples of Asymmetric SynthesisBook, Section2012
Cycloadditions and RearrangementsPrinciples of Asymmetric SynthesisBook, Section2012
Reductions and HydroborationsPrinciples of Asymmetric SynthesisBook, Section2012
OxidationsPrinciples of Asymmetric SynthesisBook, Section2012
Principles of Asymmetric SynthesisBook, Whole2012
Formal synthesis of the bisbenzylisoquinoline alkaloid berbamunine by asymmetric substitution of chiral organolithium compoundsArkivocJournal Article2011
Design and Synthesis of C(2)-Symmetric N-Heterocyclic Carbene Precursors and Metal CarbenoidsJournal of Organic ChemistryJournal Article2011
Application of a C-2-Symmetric Copper Carbenoid in the Enantioselective Hydrosilylation of Dialkyl and Aryl-Alkyl KetonesJournal of the American Chemical SocietyJournal Article2011
Application of Catalytic Dynamic Resolution of N-Boc-2-lithiopiperidine to the Asymmetric Synthesis of 2-Aryl and 2-Vinyl PiperidinesOrganic LettersJournal Article2011
NHC-catalyzed dehydrogenative self-coupling of diphenylsilane: a facile synthesis of octaphenylcyclotetra(siloxane)Tetrahedron LettersJournal Article2011
Finding Atlantis: The dual Bachelor degree in chemistry EUCHEMUSAAbstracts of Papers, 239th ACS National Meeting, San Francisco, CA, United States, March 21-25, 2010Abstract2010
Synthesis and application of a novel chiral NHC catalystAbstracts of Papers, 239th ACS National Meeting, San Francisco, CA, United States, March 21-25, 2010Abstract2010
Novel Modulator of Na(v)1.1 and Na(v)1.2 Na+ Channels in Rat Neuronal CellsACS Medicinal Chemistry LettersJournal Article2010
Signal Amplification in a Microchannel from Redox Cycling with Varied Electroactive Configurations of an Individually Addressable Microband Electrode ArrayAnalytical ChemistryJournal Article2010
The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDA. [Erratum to document cited in CA151:425101]Chemical CommunicationsJournal Article2010
Highly Enantioselective Catalytic Dynamic Resolution of; N-Boc-2-lithiopiperidine:Synthesisof(R)-(+)-N-Boc-PipecolicAcid,; (S)-(-)-Coniine,(S)-(+)-Pelletierine,(+)beta-Conhydrine,and; (S)-(-)-RopivacaineandFormalSynthesisof(-)-LasubineIIand; (+)-CermizineJournal of the American Chemical SocietyJournal Article2010
Topics in StereochemistryBook, Whole2010
Overview of carbanion dynamics and electrophilic substitutions in chiral organolithium compoundsTopics in StereochemistryBook, Section2010
PrefaceTopics in StereochemistryBook, Section2010
The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDAChemical CommunicationsJournal Article2009
Enantiomerization Dynamics and a Catalytic Dynamic Resolution of N-Trimethylallyl-2-lithiopyrrolidineJournal of the American Chemical SocietyJournal Article2009
Progress toward a microelectrochemical sensor for saxitoxin using saxiphilin c-lobeAbstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008Abstract2008
Superparamagnetic nanocrystal with dendron shell suitable for catalytic applicationAbstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008Abstract2008
New chiral Cu(I)-NHC catalyst for asymmetric cyclopropanationsAbstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008Abstract2008
Synthesis and quartz surface modification of 9,10-di-subsituted-anthracene 18-crown-6 chemosensors for the detection of saxitoxinAbstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008Abstract2008
From Tin to Lithium: Synthetic Applications and Dynamics of Chiral OrganometallicsAbstracts, 60th Southeast Regional Meeting of the American Chemical Society, Nashville, TN, United States, November 12-15, 2008Abstract2008
EUCHEMUSA: The Transatlantic Dual BS Degree in ChemistryAbstracts, 64th Southwest Regional Meeting of the American Chemical Society, Little Rock, AR, United States, October 1-4, 2008Abstract2008
New Chiral Cu(I)-NHC Catalyst for Asymmetric CyclopropanationsAbstracts, 64th Southwest Regional Meeting of the American Chemical Society, Little Rock, AR, United States, October 1-4, 2008Abstract2008
Paralytic Shellfish ToxinsAbstracts, 64th Southwest Regional Meeting of the American Chemical Society, Little Rock, AR, United States, October 1-4, 2008Abstract2008
Synthesis of 9,10-Di-Substituted-Anthracene 18-Crown-6 Chemosensors and Quartz Surface Modification for the Detection of the Paralytic Shellfish ToxinsAbstracts, 64th Southwest Regional Meeting of the American Chemical Society, Little Rock, AR, United States, October 1-4, 2008Abstract2008
Toward Electrochemical Detection of Saxitoxin: Signal Amplification by Redox Cycling at a Self-Contained Microelectrode Array in a MicrochannelAbstracts, 64th Southwest Regional Meeting of the American Chemical Society, Little Rock, AR, United States, October 1-4, 2008Abstract2008
The barrier to enantiomerization of N-Boc-2-lithiopyrrolidine: the effect of chiral and achiral diaminesChemical CommunicationsJournal Article2008
Do the terms \"% ee\" and \"% de\" make sense as expressions of stereoisomer composition or stereoselectivity? (vol 71, pg 2414, 2006)Journal of Organic ChemistryJournal Article2008
Dynamics of saxitoxin binding to saxiphilin c-lobe reveals conformational changeToxiconJournal Article2008
Organolithium chemistry: Transmetallation, electrophilic substitution, and cross-coupling reactions of organolithium with boron trifluorideAbstracts of Papers, 233rd ACS National Meeting, Chicago, IL, United States, March 25-29, 2007Abstract2007
Structures of pahayokolides A and B, cyclic peptides from a Lyngbya spJournal of Natural ProductsJournal Article2007
Visible fluorescence chemosensor for saxitoxinJournal of Organic ChemistryJournal Article2007
Configurational and conformational effects on tin-lithium exchange in alpha-aminoorganostannanes by rapid-injection NMRJournal of the American Chemical SocietyJournal Article2007
Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen YlidesOrganic LettersJournal Article2007
[2,3]-Sigmatropic rearrangements of ammonium ylidesAbstracts of Papers, 231st ACS National Meeting, Atlanta, GA, United States, March 26-30, 2006Abstract2006
Effect of crown ether ring size on binding and fluorescence response to saxitoxin in anthracylmethyl monoazacrown ether chemosensorsCanadian Journal of Chemistry-Revue Canadienne de ChimieJournal Article2006
Spectroscopic detection of Saxitoxin: an alternative to mouse bioassayChemical CommunicationsJournal Article2006
Do the terms \"% ee\" and \"% de\" make sense as expressions of stereoisomer composition or stereoselectivity?Journal of Organic ChemistryJournal Article2006
Diastereoselectivity of polar and radical couplings in electrophilic substitutions of rigid 2-lithio-N-methylpyrrolidinesOrganic and Biomolecular ChemistryJournal Article2006
Product subclass 21: alpha-lithioamines.Science of SynthesisBook, Section2006
Stannyl cyclopropanes by diastereoselective cyclopropanations with (tributylstannyl)-diazoacetate esters catalyzed by Cu(I) N-heterocyclic carbeneChemical CommunicationsJournal Article2005
Chirality made simple: A 1-and 2-dimensional introduction to stereochemistryJournal of Chemical EducationJournal Article2005
Conversion of five-, six-, and seven-membered lactams to racemic or scalemic 2-substituted heterocycles by amidoalkylationJournal of Organic ChemistryJournal Article2005
Absolute configuration of 2-(tributylstannyl)pyrrolidine by anomalous dispersion X-ray analysisJournal of Organic ChemistryJournal Article2005
Barrier to enantiomerization of unstabilized, chelated, and dipole-stabilized 2-lithiopyrrolidinesJournal of the American Chemical SocietyJournal Article2005
Heptapeptide mimic of ohmefentanyl binding in the discontinuous mu-opiod receptorOrganic LettersJournal Article2005
Structural studies of {Li-6} 2-lithiopyrrolidines using NMR spectroscopyTetrahedronJournal Article2005
Selective detection of saxitoxin over tetrodotoxin using acridinylmethyl crown ether chemosensor (vol 45, pg 783, 2005)ToxiconJournal Article2005
Selective detection of saxitoxin over tetrodotoxin using acridinylmethyl crown ether chemosensorToxiconJournal Article2005
Pharmacology and toxicology of pahayokolide A, a bioactive metabolite from a freshwater species of Lyngbya isolated from the Florida EvergladesComparative Biochemistry and Physiology C-Toxicology and PharmacologyJournal Article2004
Nucleophilic synthesis of enantiopure 2-(tributylstannyl)pyrrolidines and piperidinesTetrahedron LettersJournal Article2004
Microwave assisted solvent free amination of halo-(pyridine or pyrimidine) without transition metal catalystTetrahedron LettersJournal Article2004
Fluorescent sensors for marine toxins.Abstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003Abstract2003
Enantiomerization of unstabilized and dipole-stabilized 2-lithiopyrrolidines: (Absolute) barrier to inversionAbstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003Abstract2003
Kitching-Karplus relationship on nitrogen heterocyclesAbstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003Abstract2003
Modeling and experiment reveal an unexpected stereoelectronic effect on conformation and scalar couplings of alpha-aminoorganostannanes, with possible relevance to the tin-lithium exchange reactionJournal of Organic ChemistryJournal Article2003