CHBC Faculty Publications

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Author: Gawley, Robert E.

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TitlePublication NamePub. TypeYear
Toward the reproducibility of CuIPhEt hydrosilylationsAbstracts of Papers of the American Chemical SocietyAbstract2015
Improved synthesis and expanded application of CuIPhEt, a C-2-symmetric N-heterocyclic carbenoid.Abstracts of Papers of the American Chemical SocietyAbstract2013
Double-Asymmetric Hydrogenation Strategy for the Reduction of 1,1-Diaryl Olefins Applied to an Improved Synthesis of CuIPhEt, a C-2-Symmetric N-Heterocyclic CarbenoidJournal of Organic ChemistryJournal Article2013
Catalytic Dynamic Resolution Applied to the Synthesis of 2,6-Disubstituted Piperidines: Preparation of (+)-Lupetidine and (-)-EpidihydropinidineHeterocyclesJournal Article2012
Dynamics of Catalytic Resolution of 2-Lithio-N-Boc-piperidine by Ligand ExchangeJournal of the American Chemical SocietyJournal Article2012
Synthetic Applications and Inversion Dynamics of Configurationally Stable 2-Lithio-2-arylpyrrolidines and -piperidinesJournal of the American Chemical SocietyJournal Article2012
Introduction, General Principles, and Glossary of Stereochemical TermsPrinciples of Asymmetric SynthesisBook Section2012
Practical Aspects of Asymmetric SynthesisPrinciples of Asymmetric SynthesisBook Section2012
Enolate, Azaenolate, and Organolithium AlkylationsPrinciples of Asymmetric SynthesisBook Section2012
1,2- and 1,4-Additions to C=X BondsPrinciples of Asymmetric SynthesisBook Section2012
Aldol and Michael Additions of Allyls, Enolates, and Enolate EquivalentsPrinciples of Asymmetric SynthesisBook Section2012
Cycloadditions and RearrangementsPrinciples of Asymmetric SynthesisBook Section2012
Reductions and HydroborationsPrinciples of Asymmetric SynthesisBook Section2012
OxidationsPrinciples of Asymmetric SynthesisBook Section2012
Application of a C-2-Symmetric Copper Carbenoid in the Enantioselective Hydrosilylation of Dialkyl and Aryl-Alkyl KetonesJournal of the American Chemical SocietyJournal Article2011
Application of Catalytic Dynamic Resolution of N-Boc-2-lithiopiperidine to the Asymmetric Synthesis of 2-Aryl and 2-Vinyl PiperidinesOrganic LettersJournal Article2011
NHC-catalyzed dehydrogenative self-coupling of diphenylsilane: a facile synthesis of octaphenylcyclotetra(siloxane)Tetrahedron LettersJournal Article2011
Design and Synthesis of C-2-Symmetric N-Heterocyclic Carbene Precursors and Metal Carbenoids.Journal of Organic ChemistryJournal Article2011
Formal synthesis of the bisbenzylisoquinoline alkaloid berbamunine by asymmetric substitution of chiral organolithium compoundsArkivocJournal Article2011
Novel Modulator of Na(v)1.1 and Na(v)1.2 Na+ Channels in Rat Neuronal CellsACS Medicinal Chemistry LettersJournal Article2010
Signal Amplification in a Microchannel from Redox Cycling with Varied Electroactive Configurations of an Individually Addressable Microband Electrode ArrayAnalytical ChemistryJournal Article2010
The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDA. [Erratum to document cited in CA151:425101]Chemical CommunicationsJournal Article2010
Finding Atlantis: The dual Bachelor degree in chemistry EUCHEMUSAAbstracts of Papers of the American Chemical SocietyAbstract2010
Synthesis and application of a novel chiral NHC catalystAbstracts of Papers of the American Chemical SocietyAbstract2010
Highly Enantioselective Catalytic Dynamic Resolution of N-Boc-2-lithiopiperidine: Synthesis of (R)-(+)-N-Boc-Pipecolic Acid, (S)-(-)-Coniine, (S)-(+)-Pelletierine, (+)beta-Conhydrine, and (S)-(-)-Ropivacaine and Formal Synthesis of (-)-Lasubine II and (+)Journal of the American Chemical SocietyJournal Article2010
Overview of carbanion dynamics and electrophilic substitutions in chiral organolithium compoundsStereochemical Aspects of Organolithium Compounds: Topics in StereochemistryBook Section2010
Enantiomerization Dynamics and a Catalytic Dynamic Resolution of N-Trimethylallyl-2-lithiopyrrolidineJournal of the American Chemical SocietyJournal Article2009
The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDAChemical CommunicationsJournal Article2009
The barrier to enantiomerization of N-Boc-2-lithiopyrrolidine: the effect of chiral and achiral diaminesChemical CommunicationsJournal Article2008
From Tin to Lithium: Synthetic Applications and Dynamics of Chiral OrganometallicsAbstracts of Papers of the American Chemical SocietyAbstract2008
Paralytic Shellfish ToxinsAbstracts of Papers of the American Chemical SocietyAbstract2008
EUCHEMUSA: The Transatlantic Dual BS Degree in ChemistryAbstracts of Papers of the American Chemical SocietyAbstract2008
Synthesis of 9,10-Di-Substituted-Anthracene 18-Crown-6 Chemosensors and Quartz Surface Modification for the Detection of the Paralytic Shellfish ToxinsAbstracts of Papers of the American Chemical SocietyAbstract2008
New Chiral Cu(I)-NHC Catalyst for Asymmetric CyclopropanationsAbstracts of Papers of the American Chemical SocietyAbstract2008
Toward Electrochemical Detection of Saxitoxin: Signal Amplification by Redox Cycling at a Self-Contained Microelectrode Array in a MicrochannelAbstracts of Papers of the American Chemical SocietyAbstract2008
New chiral Cu(I)-NHC catalyst for asymmetric cyclopropanationsAbstracts of Papers of the American Chemical SocietyAbstract2008
Synthesis and quartz surface modification of 9,10-di-subsituted-anthracene 18-crown-6 chemosensors for the detection of saxitoxinAbstracts of Papers of the American Chemical SocietyAbstract2008
Superparamagnetic nanocrystal with dendron shell suitable for catalytic applicationAbstracts of Papers of the American Chemical SocietyAbstract2008
Progress toward a microelectrochemical sensor for saxitoxin using saxiphilin c-lobeAbstracts of Papers of the American Chemical SocietyAbstract2008
Do the terms "%ee" and "% de" make sense as expressions of stereoisomer composition or stereoselectivity? (vol 71, pg 2414, 2006)Journal of Organic ChemistryJournal Article2008
Dynamics of saxitoxin binding to saxiphilin c-lobe reveals conformational changeToxiconJournal Article2008
Structures of pahayokolides A and B, cyclic peptides from a Lyngbya spJournal of Natural ProductsJournal Article2007
Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen YlidesOrganic LettersJournal Article2007
Configurational and conformational effects on tin-lithium exchange in alpha-aminoorganostannanes by rapid-injection NMRJournal of the American Chemical SocietyJournal Article2007
Organolithium chemistry: Transmetallation, electrophilic substitution, and cross-coupling reactions of organolithium with boron trifluorideAbstracts of Papers of the American Chemical SocietyAbstract2007
Visible fluorescence chemosensor for saxitoxinJournal of Organic ChemistryJournal Article2007
Do the terms "% ee" and "% de" make sense as expressions of stereoisomer composition or stereoselectivity?Journal of Organic ChemistryJournal Article2006
Spectroscopic detection of Saxitoxin: an alternative to mouse bioassayChemical CommunicationsJournal Article2006
Effect of crown ether ring size on binding and fluorescence response to saxitoxin in anthracylmethyl monoazacrown ether chemosensorsCanadian Journal of Chemistry-Revue Canadienne de ChimieJournal Article2006
[2,3]-Sigmatropic rearrangements of ammonium ylidesAbstracts of Papers of the American Chemical SocietyAbstract2006
Diastereoselectivity of polar and radical couplings in electrophilic substitutions of rigid 2-lithio-N-methylpyrrolidinesOrganic and Biomolecular ChemistryJournal Article2006
Product subclass 21: a-lithioamines.Science of SynthesisJournal Article2006
Structural studies of {Li-6} 2-lithiopyrrolidines using NMR spectroscopyTetrahedronJournal Article2005
Selective detection of saxitoxin over tetrodotoxin using acridinylmethyl crown ether chemosensorToxiconJournal Article2005
Selective detection of saxitoxin over tetrodotoxin using acridinylmethyl crown ether chemosensor (vol 45, pg 783, 2005)ToxiconJournal Article2005
Barrier to enantiomerization of unstabilized, chelated, and dipole-stabilized 2-lithiopyrrolidinesJournal of the American Chemical SocietyJournal Article2005
Heptapeptide mimic of ohmefentanyl binding in the discontinuous mu-opiod receptorOrganic LettersJournal Article2005
Stannyl cyclopropanes by diastereoselective cyclopropanations with (tributylstannyl)-diazoacetate esters catalyzed by Cu(I) N-heterocyclic carbeneChemical CommunicationsJournal Article2005
Conversion of five-, six-, and seven-membered lactams to racemic or scalemic 2-substituted heterocycles by amidoalkylationJournal of Organic ChemistryJournal Article2005
Absolute configuration of 2-(tributylstannyl)pyrrolidine by anomalous dispersion X-ray analysisJournal of Organic ChemistryJournal Article2005
Chirality made simple: A 1-and 2-dimensional introduction to stereochemistryJournal of Chemical EducationJournal Article2005
Pharmacology and toxicology of pahayokolide A, a bioactive metabolite from a freshwater species of Lyngbya isolated from the Florida EvergladesComparative Biochemistry and Physiology C-Toxicology and PharmacologyJournal Article2004
Microwave assisted solvent free amination of halo-(pyridine or pyrimidine) without transition metal catalystTetrahedron LettersJournal Article2004
Nucleophilic synthesis of enantiopure 2-(tributylstannyl)pyrrolidines and piperidinesTetrahedron LettersJournal Article2004
Modeling and experiment reveal an unexpected stereoelectronic effect on conformation and scalar couplings of alpha-aminoorganostannanes, with possible relevance to the tin-lithium exchange reactionJournal of Organic ChemistryJournal Article2003
Enantiomerization of unstabilized and dipole-stabilized 2-lithiopyrrolidines: (Absolute) barrier to inversionAbstracts of Papers of the American Chemical SocietyAbstract2003
Fluorescent sensors for marine toxins.Abstracts of Papers of the American Chemical SocietyAbstract2003
Kitching-Karplus relationship on nitrogen heterocyclesAbstracts of Papers of the American Chemical SocietyAbstract2003