trans-4,4 '-dichloro-1,1 ',2,2 ',3,3 '-tetrathiadiazafulvalene (DC-TAF) and its 1 : 1 radical cation salts [DC-TAF][X]: Preparation and solid-state properties of BF4-, ClO4-, and FSO3- derivatives
by Barclay, T. M.; Beer, L.; Cordes, A. W.; Haddon, R. C.; Itkis, M. I.; Oakley, R. T.; Preuss, K. E.; Reed, R. W.
Reductive coupling of 4,5-dichloro-1,2,3-dithiazolylium chloride yields trans-4,4'-dichloro-1,1',2,2',3,3'-tetrathiadiazafulvalene (DC-TAF), the first example of this heterofulvalene system. Ab initio molecular orbital (B3LYP/6-31G**) calculations on prototypal TAF confirm that the closed shell (1)A(g) State lies 22 kcal mol(-1) below the B-3(u) diradical triplet. Cyclic voltammetry on DC-TAF reveals two reversible oxidation waves at 0.80 and 1.25 V (in CH3CN, reference SCE). The ESR signal (g = 2.0117) of the radical cation [DC-TAF](+) (in SO2(1)) exhibits a five-line hyperfine coupling pattern with a(N) = 0.096 mT. DC-TAF forms a series of 1:1 radical ion salts [DC-TAF][X] by electrooxidation in the presence of tetrahedral counterions (X- = BF4-, ClO4-, FSO3-). The crystal structures of these salts are isomorphous, monoclinic space group P2(1)/n, and consist of one-dimensional ladder-like arrays of [DC-TAF]+ radical cations bridged by S- - -S contacts ranging from 3.5 to 3.7 Angstrom. Variable-temperature conductivity and magnetic measurements on [DC-TAF][ClO4] indicate Mott insulator behavior, with a measured band gap of 0.30 eV.
- Journal
- Journal of the American Chemical Society
- Volume
- 121
- Issue
- 28
- Year
- 1999
- Start Page
- 6657-6663
- URL
- https://dx.doi.org/10.1021/ja990933z
- ISBN/ISSN
- 1520-5126; 0002-7863
- DOI
- 10.1021/ja990933z