Molecular structure of [CpRu(PPh(3))(2)(C6H11SH)]BF4 center dot CH2Cl2
by Jiang, Y. J.; Draganjac, M.; Cordes, A. W.
The structure of the [CpRu(PPh(3))(2)(C6H11SH)]BF4 . CH2Cl2 complex was determined by X-ray diffraction techniques: triclinic space group P (1) over bar, a = 12.567(1), b = 13.409(1), c = 14.733(1) Angstrom, alpha = 95.380(7), beta = 111.041(7), gamma = 96.454(8)degrees, V = 2278.5(4) Angstrom(3), Z = 2, R = 0.056, R(w) = 0.088. The Ru is attached to two triphenylphosphine ligands, a cyclopentadienyl and the S atom of the cyclohexylthiol. The Ru-S distance is 2.389(2) Angstrom and the S-H distance is 1.23 Angstrom.
- Journal
- Journal of Chemical Crystallography
- Volume
- 25
- Issue
- 10
- Year
- 1995
- Start Page
- 653-656
- URL
- https://dx.doi.org/10.1007/bf01665971
- ISBN/ISSN
- 1572-8854; 1074-1542
- DOI
- 10.1007/bf01665971