Microwave assisted solvent free amination of halo-(pyridine or pyrimidine) without transition metal catalyst

by Narayan, S.; Seelhammer, T.; Gawley, R. E.

A solvent free direct amination of halo-(pyridine or pyrimidine) has been developed in good to high yields under computer-con trolled microwave irradiation without transition metal catalyst. This reaction is a solvent and metal free, useful method for coupling of halo-(pyridine or pyrimidine) with pyrrolidine and piperidine derivatives by nucleophilic aromatic substitution (SNAr).

Journal
Tetrahedron Letters
Volume
45
Issue
4
Year
2004
Start Page
757-759
URL
https://dx.doi.org/10.1016/j.tetlet.2003.11.030
ISBN/ISSN
1873-3581; 0040-4039
DOI
10.1016/j.tetlet.2003.11.030