Pt(II)-Decorated Covalent Organic Framework for Photocatalytic Difluoroalkylation and Oxidative Cyclization Reactions
by Almansaf, Z.; Hu, J. Y.; Zanca, F.; Shahsavari, H. R.; Kampmeyer, B.; Tsuji, M.; Maity, K.; Lomonte, V.; Ha, Y. M.; Mastrorilli, P.; Todisco, S.; Benamara, M.; Oktavian, R.; Mirjafari, A.; Moghadam, P. Z.; Khosropour, A. R.; Beyzavi, H.
A new covalent organic framework (COF) based on imine bonds was assembled from 2-(4-formylphenyl)-5-formylpyridine and 1,3,6,8-tetrakis(4-aminophenyl)pyrene, which showed an interesting dual-pore structure with high crystallinity. Postmetallation of the COF with Pt occurred selectively at the N donor (imine and pyridyl) in the larger pores. The metallated COF served as an excellent recyclable heterogeneous photocatalyst for decarboxylative difluoroalkylation and oxidative cyclization reactions.
- Journal
- ACS Applied Materials and Interfaces
- Volume
- 13
- Issue
- 5
- Year
- 2021
- Start Page
- 6349-6358
- URL
- https://dx.doi.org/10.1021/acsami.0c21370
- ISBN/ISSN
- 1944-8252; 1944-8244
- DOI
- 10.1021/acsami.0c21370