Reactivity of metal dioxo complexes
by Canote, Cody A.; Kilyanek, Stefan M.
Metal dioxo chem. and its diverse reactivity are presented with an emphasis on the mechanisms of reactivity. Work from approx. the last decade is surveyed and organized by metal. In particular, the chem. of cis-dioxo metal complexes is discussed at length. Reactions are grouped by generic type, including addition across a metal oxo bond, oxygen atom transfer, and radical atom transfer reactions. Attention is given to advances in deoxygenation chem., oxidation chem., and reductive transformations.
- Journal
- Dalton Transactions
- Year
- 2024
- URL
- https://dx.doi.org/10.1039/d3dt04390h
- DOI
- 10.1039/d3dt04390h