Intramolecularly competitive Ireland Claisen rearrangements: Stereoselective synthesis of alkylidene cyclohexenes

by Zhang, X. W.; McIntosh, M. C.

Unsymmetrical bis-allyl silylketene acetals derived from cyclohexenones undergo regio- and stereoselective Ireland Claisen rearrangements to afford alkylidene cyclohexenes in good yield.

Journal
Tetrahedron Letters
Volume
39
Issue
39
Year
1998
Start Page
7043-7046
URL
https://dx.doi.org/10.1016/s0040-4039(98)01525-1
ISBN/ISSN
1873-3581; 0040-4039
DOI
10.1016/s0040-4039(98)01525-1