Preparation and Solid-State Characterization of 1,2,3,5-Diselenadiazolyl [Hcn2se2]

by Cordes, A. Wallace; Glarum, Sivert H.; Haddon, Robert C.; Hallford, Randal L.; Hicks, Robin G.; Kennepohl, Dietmar K.; Oakley, Richard T.; Palstra, Thomas T. M.; Scott, Syrona Renae Horton

The reaction of N,N,N'-tris(trimethylsilyl)formamidine with SeCl2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN2Se2].; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.

Journal
Journal of the Chemical Society-Chemical Communications
Issue
17
Year
1992
Start Page
1265
ISBN/ISSN
1364-548X; 0022-4936
DOI
10.1039/c39920001265