Cyclopentadienyl(Thioacetamide-S)-Bis(Triphenylphosphine-P)Ruthenium(Ii) Tetrafluoroborate
by Bryan, C. D.; Cordes, A. W.; Draganjac, M.
The title compound [Ru(C5H5)(C2H5NS)(C18H15P)(2)]-BF4 crystallizes in the space group P2(1)/c. The Ru atom has pseudotetrahedral coordination geometry formed by the cyclopentadienyl centroid, the two PPh(3) ligands and the 5 atom of the neutral thioacetamide molecule. The Ru-S and C=S distances are 2.3820 (13) and 1.671 (5) Angstrom, respectively, and the Ru-S=C angle is 116.3 (2)degrees. The Ru atom is at a distance of 0.405 (9) Angstrom from the plane formed by the atoms of the thioacetamide group.
- Journal
- Acta Crystallographica Section C-Crystal Structure Communications
- Volume
- 50
- Year
- 1994
- Start Page
- 1231-1233
- URL
- https://dx.doi.org/10.1107/s0108270194003495
- ISBN/ISSN
- 1600-5759; 0108-2701
- DOI
- 10.1107/s0108270194003495