Colloidal CdSe quantum wires by oriented attachment

by Pradhan, N.; Xu, H. F.; Peng, X. G.

We report here a relatively low temperature (1100-180 degrees C) synthetic route to high-quality and single-crystalline CdSe nanowires using air-stable and generic chemicals. The diameter of nanowires was controlled and varied in an exceptionally small size regime, between 1.5 and 6 nm. This was achieved by using alkylamines, a single type or a mixture of two different types of amines, with different chain lengths and varying the reaction temperature. The experimental results suggest the coexistence of two types of fragments in the prewire aggregates, known as "pearl-necklace" or "string-of-pearls" in the literature, which are loosely associated and chemically fused sections.

Journal
Nano Letters
Volume
6
Issue
4
Year
2006
Start Page
720-724
URL
https://dx.doi.org/10.1021/nl052497m
ISBN/ISSN
1530-6992; 1530-6984
DOI
10.1021/nl052497m