Intramolecularly competitive Ireland Claisen rearrangements: Stereoselective synthesis of alkylidene cyclohexenes

by Zhang, Xiaowei; McIntosh, Matt C.

Unsymmetrical bis-allyl silylketene acetals derived from cyclohexenones undergo regio- and stereoselective Ireland Claisen rearrangements to afford alkylidene cyclohexenes in good yield. (C) 1998 Elsevier Science Ltd. All rights reserved.

Journal
Tetrahedron Letters
Volume
39
Issue
39
Year
1998
Start Page
7043
ISBN/ISSN
1873-3581; 0040-4039
DOI
10.1016/S0040-4039(98)01525-1