Copper(Ii) and Cobalt(Ii) Complexes of 2,2-Diphenyl-4,4,6,6-Tetrakis(1-Pyrazolyl)Cyclotriphosphazene, N(3)P(3)Ph(2)Pz(4) - X-Ray Crystal-Structure of N(3)P(3)Ph(2)Pz(4)Center-Dot-Cocl2-Center-Dot-0.5ch(2)Cl(2)
by Thomas, K. R. J.; Chandrasekhar, V.; Scott, S. R.; Cordes, A. W.
Synthesis and characterization of isotypical compounds N(3)P(3)Ph(2)Pz(4) . MX(2) (M = Cu, X = Cl or Br; M = Co, X = Cl) are reported. The X-ray crystal structure of N(3)P(3)Ph(2)Pz(4) . CoCl2 . 0.5CH(2)Cl(2) is described. The structure is a distorted trigonal bipyramid in which the cobalt atom is coordinated by a ligand molecule through the two nongeminal pyrazolyl pyridinic nitrogens at the equatorial sites and a cyclophosphazene ring nitrogen at the axial position. The remaining axial and equatorial positions are occupied by the two chlorine atoms.
- Journal
- Polyhedron
- Volume
- 14
- Issue
- 12
- Year
- 1995
- Start Page
- 1607-1613
- URL
- https://dx.doi.org/10.1016/0277-5387(94)00434-g
- ISBN/ISSN
- 1873-3719; 0277-5387
- DOI
- 10.1016/0277-5387(94)00434-g