Preparation, Structure and Chemistry of a Novel, Disjoint Diradical, 4,4'-Bis(1,2,3,5-Dithiadiazolyl)
by Hicks, R. G.; Mackinnon, C. D.; Oakley, R. T.; Bryan, C. D.; Cordes, A. W.; Haddon, R. C.
The reaction of oxamidrazone with SCl2 affords 4,4'-bis(1,2,3,5-dithiadiazolium) dichloride, which can be reduced to the corresponding bis(1,2,3,5-dithiadiazolyl) diradical; the electronic structure of the diradical is discussed, and the solid state structure, charge transfer chemistry and transport properties of the dimer [S2N2CCN2S2](2) are described.
- Journal
- Phosphorus, Sulfur and Silicon and the Related Elements
- Volume
- 93
- Issue
- 1-4
- Year
- 1994
- Start Page
- 439-440
- URL
- https://dx.doi.org/10.1080/10426509408021893
- ISBN/ISSN
- 1563-5325; 1042-6507
- DOI
- 10.1080/10426509408021893