Organocobaloximes with mixed-dioxime equatorial ligands: a one-pot synthesis

by Gupta, B. D.; Singh, Veena; Qanungo, Kushal; Vijaikanth, V.; Yamuna, R.; Barclay, Tosha Madeva; Cordes, A. Wallace

BenzylCo(dmgH)(dpgH)Py has been synthesized by the reaction of benzyl chloride with a mixture of Co-1(dmgH)(2)Py and Co-1(dpgH)(2)Py, generated in situ, by the NaBH4 reduction of ClCo(dmgH)(2)Py and ClCo(dpgH)(2)Py. A mixture of three products is formed. The first crystal structure of an organocobaloxime with a mixed-dioxime ligand is reported. (C) 2000 Elsevier Science S.A. All rights reserved.

Journal
Journal of Organometallic Chemistry
Volume
602
Issue
1-2
Year
2000
Start Page
1
ISBN/ISSN
1872-8561; 0022-328X
DOI
10.1016/S0022-328X(00)00105-4