A 1,2,3,5-dithiadiazolyl dimeric radical cation. Preparation and solid state characterization of 1,3-[(S2N2C)C6H4(CN2S2)](2)[Cl](3)
by Britten, J. F.; Cordes, A. W.; Haddon, R. C.; Itkis, M. E.; Oakley, R. T.; Reed, R. W.; Robertson, C. M.
The biradical 1,3-benzene-bis(1,2,3,5-dithiadiazolyl) [1,3-S] forms a mixed valence salt [1,3-S]2[Cl]3 by controlled oxidation with chlorine. The structure of this salt contains a dimeric radical cation [CN2S2](2)(+), the first example of this unit in dithiadiazolyl chemistry. Variable temperature magnetic susceptibility measurements indicate a strongly antiferromagnetically coupled system.
- Journal
- CrystEngComm
- Volume
- 4
- Year
- 2002
- Start Page
- 205-207
- URL
- https://dx.doi.org/10.1039/b204999f
- ISBN/ISSN
- 1466-8033
- DOI
- 10.1039/b204999f