CHBC Faculty Publications

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Author: McIntosh, Matthias C.

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TitlePublication NamePub. TypeYear
Radical homolysis of pyridine-based Breslow-like enaminolsAbstracts of Papers of the American Chemical SocietyAbstract2023
Two-step derivatization of fluconazole via radical fragmentation of a Breslow-type intermediate.Abstracts of Papers of the American Chemical SocietyAbstract2018
Thermal azole based Claisen rearrangements.Abstracts of Papers of the American Chemical SocietyAbstract2018
Oka fragmentation of the Breslow intermediate is a radical process.Abstracts of Papers of the American Chemical SocietyAbstract2018
Two-step derivatization of fluconazole via radical fragmentation of a Breslow-type intermediate.Abstracts of Papers of the American Chemical SocietyAbstract2018
Low-temperature C-N and C-O sigma bond homolysis: Recent experimental and computational results.Abstracts of Papers of the American Chemical SocietyAbstract2018
Fragmentation of the Breslow intermediate is a radical process.Abstracts of Papers of the American Chemical SocietyAbstract2018
Radical chemistry of the Breslow intermediate.Abstracts of Papers of the American Chemical SocietyAbstract2017
Acyclic 1,4-Stereocontrol via the Allylic Diazene Rearrangement: Development, Applications, and the Essential Role of Kinetic E Stereoselectivity in Tosylhydrazone FormationJournal of Organic ChemistryJournal Article2017
Genetically encoding thioacetyl-lysine as a non-deacetylatable analog of lysine acetylation in Escherichia coliFEBS Open BioJournal Article2017
Radical [1,3] Rearrangements of Breslow IntermediatesAngewandte Chemie-International EditionJournal Article2016
Radical chemistry of the Breslow intermediateAbstracts of Papers of the American Chemical SocietyAbstract2016
Toward the reproducibility of CuIPhEt hydrosilylationsAbstracts of Papers of the American Chemical SocietyAbstract2015
Progress and efforts toward the asymmetric total synthesis of antascomicin BAbstracts of Papers of the American Chemical SocietyAbstract2015
Progress of the total asymmetric synthesis of antascomicin BAbstracts of Papers of the American Chemical SocietyAbstract2015
Natural products inspired synthesisAbstracts of Papers of the American Chemical SocietyAbstract2015
Recent advances in azole-based Claisen rearrangementsAbstracts of Papers of the American Chemical SocietyAbstract2014
Rearrangement of the Breslow intermediateAbstracts of Papers of the American Chemical SocietyAbstract2014
Intercepting the Breslow intermediate via Claisen rearrangement: Synthesis of complex 3 degrees alcohols without organometallic reagentsAbstracts of Papers of the American Chemical SocietyAbstract2013
New directions for the Breslow intermediateAbstracts of Papers of the American Chemical SocietyAbstract2013
Intercepting the Breslow Intermediate via Claisen Rearrangement: Synthesis of Complex Tertiary Alcohols without Organometallic ReagentsOrganic LettersJournal Article2013
Isobenzofuran analogs of sclerophytin APatent2013
Anomalies in the asymmetric transfer hydrogenation of several polycyclic meso compoundsTetrahedron LettersJournal Article2012
[3,3]-Sigmatropic rearrangements of N-allyl-S,N-ketene acetalsAbstracts of Papers of the American Chemical SocietyAbstract2012
Anomalies in the Noyori asymmetric transfer hydrogenation of several polycyclic meso compoundsAbstracts of Papers of the American Chemical SocietyAbstract2012
Toward the total synthesis of Antascomicin B: Building the C10-C21 fragmentAbstracts of Papers of the American Chemical SocietyAbstract2012
Further studies on the allylic diazene rearrangement (ADR)Abstracts of Papers of the American Chemical SocietyAbstract2012
Synthesis of trans-epoxy quinol via Noyori asymmetric transfer hydrogenation of meso-epoxy diketoneAbstracts of Papers of the American Chemical SocietyAbstract2012
Toward the total synthesis of antascomicin B: Building the C10-C16 fragment.Abstracts of Papers of the American Chemical SocietyAbstract2011
Methods towards thiazolium salt rearrangements.Abstracts of Papers of the American Chemical SocietyAbstract2011
Toward a scalable asymmetric synthesis of (4R,5S,6R) Trihydroxycyclohexen-2-oneAbstracts of Papers of the American Chemical SocietyAbstract2011
Progress toward the synthesis of Antascomicin BAbstracts of Papers of the American Chemical SocietyAbstract2011
Synthesis of the C21-C34 fragment of antascomicin BTetrahedron LettersJournal Article2011
Efficient, scalable asymmetric synthesis of an epoxy quinol via Noyori desymmetrization of a meso diketoneTetrahedron-AsymmetryJournal Article2011
Studies directed toward the synthesis of the massileunicellins. Part 2Tetrahedron LettersJournal Article2010
Synthetic studies toward antascomicin BPacifichem 2010, International Chemical Congress of Pacific Basin Societies, Honolulu, HI, United States, December 15-20, 2010Abstract2010
Organic LinkingACS Chemical BiologyJournal Article2010
New applications of the allylic diazene rearrangementAbstracts of Papers of the American Chemical SocietyAbstract2010
Toward the total synthesis of Antascomicin B via amino Claisen and allylic diazene rearrangement sequenceAbstracts of Papers of the American Chemical SocietyAbstract2010
Novel SN2' reactions in terpenoid synthesisAbstracts of Papers of the American Chemical SocietyAbstract2010
Total synthesis - molecules and medicine: A documentary filmAbstracts of Papers of the American Chemical SocietyAbstract2010
Studies toward the C22-C34 fragment of antascomicin BAbstracts of Papers of the American Chemical SocietyAbstract2010
Toward the asymmetric synthesis of the C17-C34 fragment of antascomicin B via an Ireland Claisen (ICR) and allylic diazene (ADR) rearrangement sequenceAbstracts of Papers of the American Chemical SocietyAbstract2010
Toward solutions to the problem of controlling E-O-enolate geometry in Ireland-Claisen rearrengements transition stateAbstracts of Papers of the American Chemical SocietyAbstract2010
Toward the synthesis of sclerophytin AAbstracts of Papers of the American Chemical SocietyAbstract2010
Toward the asymmetric total synthesis of antascomicin B via an asymmetric transfer hydrogenation, an Ireland-Claisen (ICR), and an allylic diazene (ADR) rearrangement sequenceAbstracts of Papers of the American Chemical SocietyAbstract2010
Synthesis Toward Antascomicin BAbstracts of Papers of the American Chemical SocietyAbstract2009
Toward the synthesis of the C22-C34 fragment of antascomicin B via an allylic diazene (ADR) and Ireland Claisen (ICR) rearrangementAbstracts of Papers of the American Chemical SocietyAbstract2009
Toward the synthesis of sclerophytin AAbstracts of Papers of the American Chemical SocietyAbstract2009
Toward the total synthesis of antascomicin B via in Ireland-Claisen and allylic diazene rearrangement sequenceAbstracts of Papers of the American Chemical SocietyAbstract2009
New applications of the allylic diazene rearrangementAbstracts of Papers of the American Chemical SocietyAbstract2009
Toward a chemistry documentary on total synthesisAbstracts of Papers of the American Chemical SocietyAbstract2009
Synthesis and anticancer activity of sclerophytin-inspired hydroisobenzofuransBioorganic and Medicinal Chemistry LettersJournal Article2009
Toward the synthesis of antascomicin B. Synthesis of a model of the C22-C34 fragment via Ireland-Claisen and allylic diazene rearrangementsTetrahedronJournal Article2008
Acyclic 1,4-stereocontrol via reductive 1,3-transpositionsOrganic LettersJournal Article2008
New Applications of the Allylic Diazene RearrangementAbstracts of Papers of the American Chemical SocietyAbstract2008
Towards the Synthesis of the C22-C34 Fragment of Antascomicin BAbstracts of Papers of the American Chemical SocietyAbstract2008
Approach to the total synthesis of Massileunicellin CAbstracts of Papers of the American Chemical SocietyAbstract2007
Diastereoselective acyclic allylic diazene rearrangementAbstracts of Papers of the American Chemical SocietyAbstract2007
Model studies toward the synthesis of the C22-34 fragment of antascomicin-BAbstracts of Papers of the American Chemical SocietyAbstract2007
The Ireland-Claisen rearrangement (1972-2004)The Claisen Rearrangement: Methods and ApplicationsBook Section2007
Approach to the synthesis of Cladiell-11-ene-3,6,7-triolOrganic LettersJournal Article2006
Progress toward the total synthesis of Sclerophytin AAbstracts of Papers of the American Chemical SocietyAbstract2006
Approach to the total synthesis of massileunicellin-IAbstracts of Papers of the American Chemical SocietyAbstract2005
Progess toward the total synthesis of sclerophytin AAbstracts of Papers of the American Chemical SocietyAbstract2005
High throughput synthesis of novel isobenzoifuran based drug candidates for the treatment of cancerAbstracts of Papers of the American Chemical SocietyAbstract2005
Model studies toward the synthesis of the C22-34 fragment of antascomicin-BAbstracts of Papers of the American Chemical SocietyAbstract2005
Unprecedented alkene stereocontrol in the Claisen rearrangement of cyclic bis-allylic estersOrganic LettersJournal Article2005
A convenient 3-step synthesis of (R)-7-hydroxycarvone from (S)-alpha-pineneJournal of Organic ChemistryJournal Article2005
Improved alkylation and product stability in phosphotriester formation through quinone methide reactions with dialkyl phosphatesJournal of Organic ChemistryJournal Article2005
Improved alkylation and product stability in phosphotriester formation through quinone methide reactions with dialkyl phosphates. (vol 70, pg 4345, 2005)Journal of Organic ChemistryJournal Article2005
Studies directed toward the synthesis of the massileunicellinsTetrahedron LettersJournal Article2004
An Ireland-Claisen approach to lignans: Synthesis of the putative structure of 5-epi-eupomatilone-6Journal of Organic ChemistryJournal Article2004
Approach to the total synthesis of massileunicellin-DAbstracts of Papers of the American Chemical SocietyAbstract2004
Model studies directed toward the synthesis of the C22-C34 fragment of antascomicin-BAbstracts of Papers of the American Chemical SocietyAbstract2004
Progress toward the total synthesis of sclerophytin AAbstracts of Papers of the American Chemical SocietyAbstract2004
Cu-mediated alkoxystannane addition to an allylic lactone: Application to the synthesis of sclerophytin AAbstracts of Papers of the American Chemical SocietyAbstract2004
Approach to the Synthesis of the MassileunicellinsAbstracts of Papers of the American Chemical SocietyAbstract2004
Cycloaldol approach to the isobenzofuran core of eunicellin diterpenesOrganic LettersJournal Article2003
An approach to the synthesis of the eupomatilonesOrganic LettersJournal Article2002
Intramolecularly competitive Ireland-Claisen rearrangements: Scope and potential applications to natural product synthesisJournal of Organic ChemistryJournal Article2002
New aspects of the Ireland and related Claisen rearrangementsTetrahedronJournal Article2002
Synthesis of the C-2-C-5 fragment of eleutherobin.Abstracts of Papers of the American Chemical SocietyAbstract2002
Approaches to the synthesis of the eupomatilones.Abstracts of Papers of the American Chemical SocietyAbstract2002
Progress toward the asymmetric synthesis of the hydroisobenzofuran nucleus of eunicellin diterpenes.Abstracts of Papers of the American Chemical SocietyAbstract2002
Effect of structure on diastereoselection in an intramolecular SN2' reaction.Abstracts of Papers of the American Chemical SocietyAbstract2002
New applications of the Ireland Claisen rearrangement in natural product synthesis.Abstracts of Papers of the American Chemical SocietyAbstract2001
Progress toward the synthesis of the eupomatilones.Abstracts of Papers of the American Chemical SocietyAbstract2001
Studies toward the total synthesis of eleutherobin via an Ireland-Claisen rearrangement.Abstracts of Papers of the American Chemical SocietyAbstract2001
Diastereoselectivity in the 1,2 addition of hard nucleophiles to C-6-substituted cyclohexenones.Abstracts of Papers of the American Chemical SocietyAbstract2001
Studies directed toward the synthesis of eleutherobin.Abstracts of Papers of the American Chemical SocietyAbstract2001
Unusual reagent control of diastereoselectivity in the 1,2-addition of hard carbon nucleophiles to C-6-heteroatom substituted cyclohexenonesOrganic LettersJournal Article2001
A simple C-13 NMR method for determination of the relative stereochemistry of 2,3-dialkylpentenoic acids and related compoundsTetrahedronJournal Article2001
Early exposure of undergraduates to the chemistry research environment: A new model for resource universitiesJournal of Chemical EducationJournal Article2000
Regio- and stereoselective oxidative difunctionalization of alkylidene cyclohexenesTetrahedron LettersJournal Article2000
Progress toward the synthesis of eunicellin diterpenes.Abstracts of Papers of the American Chemical SocietyAbstract2000
Exo-selective Ireland Claisen rearrangement: Scope and applications.Abstracts of Papers of the American Chemical SocietyAbstract2000
Control of ring-side chain relative stereochemistry via stereoselective functionalization of alkylidene cycloalkenes.Abstracts of Papers of the American Chemical SocietyAbstract1999
Electrophile triggering via an Ireland Claisen rearrangement: Novel synthesis of cyclohexadienyl lactones and cyclopropanes.Abstracts of Papers of the American Chemical SocietyAbstract1999
New applications of the Ireland Claisen rearrangement in natural products synthesis.Abstracts of Papers of the American Chemical SocietyAbstract1999
Comparison of ester enolate and silylketene acetal variants of the Ireland Claisen rearrangements in bis-allylic substratesAbstracts of Papers of the American Chemical SocietyAbstract1999
Synthesis of diversely functionalized lactones and lactams via regioselective oxidations of alkylidene cyclohexenes.Abstracts of Papers of the American Chemical SocietyAbstract1999
An approach to the indolizidine nucleus by tandem conjugate addition reactions.Abstracts of Papers of the American Chemical SocietyAbstract1998
Regio- and stereoselective claisen rearrangement of unsymmetrical bis-allyl silylketene acetals.Abstracts of Papers of the American Chemical SocietyAbstract1998
Progress toward the synthesis of the A-G ring spiroimine of pinnatoxin A.Abstracts of Papers of the American Chemical SocietyAbstract1998
Formation of vicinal quaternary carbon centers via the Ireland Claisen rearrangement.Abstracts of Papers of the American Chemical SocietyAbstract1998
Impact of a brief research experience on undergraduates' attitude toward science.Abstracts of Papers of the American Chemical SocietyAbstract1998
Intramolecularly competitive Ireland Claisen rearrangements: Stereoselective synthesis of alkylidene cyclohexenesTetrahedron LettersJournal Article1998