Flexible and sewable electrode based on Ni-Co@PANI-salphen composite-coated on textiles for wearable supercapacitor
by Adriyani, T. R.; Ensafi, A. A.; Rezaei, B.
Flexible electrodes with high deformability and energy density are critical for electronic textiles. The key factor for achieving high-performance supercapacitors with superior power and energy density is the evaluation of materials that exhibit exceptional capacitive performance. Herein, we have prepared Ni-Co nanoparticles at the surface of polyaniline-salphen (Ni-Co@PS). Then, followed by casting Ni-Co@PS on a conductive carbon cloth (CC) as a substrate through a facile in-situ polymerization strategy. The morphologies of Ni-Co@PS composite were characterized by different methods such as FE-SEM, XPS, XRD, BET, and electrochemical methods. This nanocomposite showed high tolerability and a large surface area with excellent behavior as a new nanomaterial for supercapacitor application. Thus, the optimum composite designed with a metal ratio (nickel-cobalt 3:1 w/w) satisfactorily possesses a specific capacitance of up to 549.994 C g-1 (1447.2 F g-1) under 0.5 A g-1 and long-term cyclic stability featuring capacity retention of 95.9% after 5000 cycles at a current density of 9.0 A g-1. The Ni-Co@PS-CC, is a material with great potential as an electrode in asymmetric wearable supercapacitor (AWSC) apparatus, demonstrating a remarkable specific capacity of 70.01, and accompanied by an energy density of 23.46 Wh k g-1 at a power density of 800 W k g-1.
- Journal
- Scientific Reports
- Volume
- 13
- Issue
- 1
- Year
- 2023
- Start Page
- 13
- URL
- https://dx.doi.org/10.1038/s41598-023-47067-y
- ISBN/ISSN
- 2045-2322
- DOI
- 10.1038/s41598-023-47067-y